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General comments This study describes chamber studies of the chemistry of secondary organic aerosol (SOA) formation from the reactions of isoprene with nitrate radicals, illustrates the formation mechanisms of the multi-generation organic nitrates, investigates the volatilities of organic nitrates using both parametrization and experimental methods, and evaluates their potential to form SOA. The paper is well written, and the experiments and data analysis are well done. The mechanisms that aredoi:10.5194/acp-2020-1180-rc1 fatcat:3s5a5joembfofoomenyc662u2u