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Mean field and the confined single homopolymer
2009
Molecular Physics
We develop a statistical model for a confined chain molecule based on a monomer grand canonical ensemble. The molecule is subject to an external chemical potential, a backbone interaction, and an attractive interaction between all monomers. Using a Gaussian variable formalism and a mean field approximation, we analytically derive a minimum principle from which we can obtain relevant physical quantities, such as the monomer density, and we explore the limit in which the chain is subject to a
doi:10.1080/00268970902776740
fatcat:7zwcrgy4nbaunhhno54i5fgmem