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Methylene blue catalyzes the visible light-induced organocatalytic α-oxyamination of aldehydes via enamines. The irradiation of 3-phenylpropanal with TEMPO radical in the presence of morpholine as an organocatalyst and methylene blue as a photoredox catalyst gave the desired α-functionalized aldehyde in 75% yield.doi:10.3998/ark.5550190.p009.769 fatcat:tqbqxx5imbdphadhftcdj7cika