Effect of Surfactant on Rheological and Electrical Properties of Latex-Blended Polystyrene/Single-Walled Carbon Nanotube Nanocomposites
계면활성제가 라텍스 블렌딩 폴리스티렌/단일벽 탄소나노튜브 나노복합재료의 유변학적, 전기적 물성에 미치는 영향

Myung-Hwan Kang, Won-Jin Noh, Dong-Kyun Woo, Seong-Jae Lee
2012 Porrime  
Polystyrene/single-walled carbon nanotube (PS/SWCNT) nanocomposites were prepared by latex technology and the effect of surfactant (SDS) on nanotube dispersion, rheological and electrical properties was investigated. The nanocomposites were prepared through freeze-drying after mixing PS particles and aqueous SWCNT/SDS suspension. As the SDS content increased, the storage modulus and complex viscosity of the nanocomposites were increased due to enhanced dispersion of nanotubes, but if the
more » ... excessively increased, the modulus and viscosity began to decrease due to low molecular weight of SDS. The electrical conductivity sharply increased with the addition of SDS, and then did not show significant changes. This result is speculated to be the competition between the increased dispersion of nanotubes and the deterioration of electrical conductivity by SDS adsorption. An optimal ratio of SDS to SWCNT for improving electrical conductivity and end-use properties was 2. With this ratio, the electrical percolation threshold of SWCNT was less than 1 wt%.
doi:10.7317/pk.2012.36.3.364 fatcat:3zngaacrmfgmzcmpsty2brsfc4