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Unexpected Selective Gas Adsorption on A 'Non-Porous' Metal Organic Framework
2020
Crystals
A metal organic framework Cu(tpt)BF4·¾H2O was synthesized as a potential carbon capture material, with the aim being to exploit the Lewis base interaction of the incorporated ligand functionalities with acidic gas. The material displays high thermal stability but an exceptionally low surface area; however, this contrasts starkly with its ability to capture carbon dioxide, demonstrating significant activated diffusion within the framework. The full characterization of the material shows a robust
doi:10.3390/cryst10060548
fatcat:saouul3c6bfa7l7iweenh22ycm