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Reversible deformation and molecular reorientation exhibited by smectic main-chain elastomers
主鎖型高分子液晶を用いたポリマーネットワークの可逆変形と分子再配列
2008
Preprints of symposium on liquid crystals
主鎖型高分子液晶を用いたポリマーネットワークの可逆変形と分子再配列
We observed spontaneous shape change of a uniaxially deformed liquid-crystalline elastomer composed of smectic main-chain liquid-crystalline polyesters with varying temperature in a cyclic heating-cooling process. Although the elastomer contracted about 115 % ((L-Liso)/Liso x 100) on heating up to the isotropic phase, the sample length recovered only 55 % on cooling to room temperature in the first heating-cooling process, the elastomer exhibited almost complete reversible deformation in the
doi:10.11538/ekitou.2008.0.36.0
fatcat:7jbv4enifrgx3muv2vrwm4ia6e