CO on Pt(111): A puzzle revisited

R. A. Olsen, P. H. T. Philipsen, E. J. Baerends
2003 Journal of Chemical Physics  
Today's state-of-the-art method for calculating the interaction of atoms or small molecules with metal surfaces is considered to be density functional theory ͑DFT͒ at the generalized gradient approximation ͑GGA͒ level employing a slab or supercell representation of the surface. The method is widely used and by many assumed to be both qualitatively and quantitatively accurate. This notion has recently been challenged by Feibelman et al. ͓J. Phys. Chem. B 105, 4018 ͑2001͔͒ who suggest that the
more » ... suggest that the DFT/GGA method does not correctly predict the most stable adsorption site for the CO/Pt͑111͒ system, and they conclude that the method is not qualitatively accurate. However, using a different calculational approach we find a good agreement between the calculated potential energy surface for this system and the one inferred from experiments, indicating that the evidence supporting the view of Feibelman et al. is not yet conclusive. On the contrary, we advocate the view that the DFT/GGA method should at the moment be considered qualitatively accurate for predicting the most stable CO adsorption sites on metal surfaces. This view is supported by ͑i͒ our results for the Pt͑111͒ surface which in agreement with experiments favors the top site, ͑ii͒ an assessment of literature results for other surfaces, suggesting that the error in the relative stability of the CO adsorption sites on a given surface is within Ϯ0.1 eV when compared to experiments, ͑iii͒ the considerable challenge one faces when trying to converge DFT/GGA calculations within Ϯ0.1 eV with respect to all computational parameters, ͑iv͒ and that for energy differences smaller than say 0.1 eV, calculated quantities like, e.g., vibrational frequencies and geometries discriminate correctly between sites, being in agreement with experiments at the correct adsorption site.
doi:10.1063/1.1593629 fatcat:362abdfq7jbltpl5pwldy4o5sm