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Singly Occupied Molecular Orbital−Highest Occupied Molecular Orbital (SOMO−HOMO) Conversion
2021
Australian journal of chemistry (Print)
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Singly occupied molecular orbitalÀhighest occupied molecular orbital (SOMOÀHOMO) conversion (inversion), SHC, is a phenomenon in which the SOMO is lower in energy than the doubly occupied molecular orbitals (DOMO, HOMO). A non-Aufbau electronic structure leads to unique properties such as a switch in bond dissociation energy and the generation of high-spin species on one-electron oxidation. In addition, the pronounced photostability of these species has been reported recently for application in
doi:10.1071/ch21186
fatcat:2cpi4ih3ljfbtns7s4fefn5jmq