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Enhancement of lanthanide evaporation by complexation: Dysprosium tri-iodide mixed with indium iodide and thulium tri-iodide mixed with thallium iodide
2013
Journal of Chemical Physics
The vapors in equilibrium with condensates of DyI 3 , DyI 3 /InI, TmI 3 , and TmI 3 /TlI were observed over the temperature range from 900 K to 1400 K using x-ray induced fluorescence. The total densities of each element (Dy, Tm, In, Tl, and I) in the vapor, summed over all atomic and molecular species, were determined. Dramatic enhancements in the total vapor densities of Dy and Tm were observed in the vapors over DyI 3 /InI and TmI 3 /TlI as compared to the vapors over pure DyI 3 and pure TmI
doi:10.1063/1.4821828
pmid:24089770
fatcat:tfelfozsqrgktcyattt2wmiywu