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Two pathways of proton transfer reaction to (triphos)Cu(η1-BH4) via a dihydrogen bond [triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane]
2016
Dalton Transactions
The interaction of alcohols of variable strength with the copper(i) borohydride complex (triphos)Cu(η1-BH4) results in a great variety of DHB complexes which encompass different mechanisms involving M–H and E–H bond (E = B, O) activation steps.
doi:10.1039/c6dt01104g
pmid:27163554
fatcat:wodjejba6bbwhd4wlfy6rw4xpm