Two pathways of proton transfer reaction to (triphos)Cu(η1-BH4) via a dihydrogen bond [triphos = 1,1,1-tris(diphenylphosphinomethyl)ethane]

I. E. Golub, O. A. Filippov, N. V. Belkova, L. M. Epstein, A. Rossin, M. Peruzzini, E. S. Shubina
2016 Dalton Transactions  
The interaction of alcohols of variable strength with the copper(i) borohydride complex (triphos)Cu(η1-BH4) results in a great variety of DHB complexes which encompass different mechanisms involving M–H and E–H bond (E = B, O) activation steps.
doi:10.1039/c6dt01104g pmid:27163554 fatcat:wodjejba6bbwhd4wlfy6rw4xpm