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Fast and Selective Photoreduction of CO2 to CO Catalyzed by a Complex of Carbon Monoxide Dehydrogenase, TiO2, and Ag Nanoclusters
[component]
unpublished
Selective, visible light-driven conversion of CO 2 to CO with a turnover frequency of 20 s −1 under visible light irradiation at 25 o C is catalyzed by an aqueous colloidal system comprising a pseudo-ternary complex formed between carbon monoxide dehydrogenase (CODH), silver nanoclusters stabilized by polymethacrylic acid (AgNCs-PMAA) and TiO 2 nanoparticles. The photocatalytic assembly which is stable over several hours and for at least 250,000 turnovers of the enzyme's active site, was
doi:10.1021/acscatal.7b04308.s001
fatcat:dmt74aljffhvhokaeczj23c6vy