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Preparation of poly(ethylcyanoacrylate) nanofibers by vapor phase polymerization using alcohol initiators
unpublished
Anionic initiators, containing either hydroxyl or thiohydroxyl group as initiating moieties, were used for preparation of poly(ethylcynoacrylate) (PECA) nanofibers by vapor phase polymerization. The hydroxyl (alcohol) and thoalcohol groups as nucleophilic entities are capable to attack the double bond of monomer resulting in polymerization in vapor phase and formation of nanofibers at high relative humidity atmosphere. Different techniques such as scanning electron microscopy, thermogravimetric
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