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Studies in the coordination chemistry of certain transition metals
[article]
2013
A number of new adducts of the metal-halogen cluster Mo₆Cl₈⁴⁺ have been prepared and characterized. Monodentate ligands generally yield complexes of the type [(Mo₆Cl₈)Cl₄2L]; these compounds show only low ionization in donor solvents and are amorphous to X-rays. On the other hand, bidentate ligands form crystalline derivatives of composition [(Mo₆Cl₈)Cl₄(L)₂]Cl₂ or [(Mo₆Cl₈)Cl₃L]Cl. The noteworthy features of these adducts is the characteristic six-fold coordination to the cluster, irrespective
doi:10.26021/7386
fatcat:zhosiofxdzflfgo2ssssigmp7m