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Generalized quantum Fokker–Planck theory and its application to laser driven intramolecular hydrogen transfer reactions in condensed phases
2000
Journal of Chemical Physics
A generalized quantum Fokker-Planck theory is proposed to treat the correlated dynamics of coherent driving and Markovian dissipation. The resulting formulation is applicable to arbitrary external time-dependent driving fields and satisfies the detailed balance condition at arbitrary temperatures. Analyzed are also the formal relations among the Caldeira-Leggett quantum Fokker-Planck equation, the Bloch-Redfield theory, and the present formulation. The approach is numerically implemented to
doi:10.1063/1.481212
fatcat:weerkcc6rzb5jm657f45sl43um