Polarographic behaviour of Cull-2,4,6-trihydroxy-deoxy-benzoin ethanol-water (65%) media complexes in

V. K. Sharma
2012 Zenodo  
Department of Chemistry, Shyam Lal College (University of Delhi), Shahdara, Delhi-I 10 032, India E-mail· drvinodsharma57 @yahoo. com Manuscript . received 16 August 201 J, revised 09 January 2012. accepted 10 January 2012 Polarographic behaviour of 2,4,6-trihydroxy-deoxy-benzoin with CuII ion in 65% ethanol-water media has been investigated. Crow's mean diffusion coefficient (utilizing diffusion current values) and DeFord-Home's (using halfwave potential values) methods were applied to
more » ... e the stability constant values of complexes. Cull forms 1 : 1 and 1 : 2 complexes with 2,4,6-trihydroxy-deoxy-benzoin. The studies were carried out at different temperatures to calculate thermodynamic parameters, the change in Gibb's free energy, change In enthalpy and change in entropy.
doi:10.5281/zenodo.5771342 fatcat:stfkjnzkhfh2bebwnmb4zot23e