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The Determination of Absolute Rate Constants in Olefinic Oxidations
1948
Proceedings of the Royal Society A
On the basis of the reaction mechanism established in the preceding paper (this volume, p. 376), the changes in rate of photo-oxidation observed in intermittent light when a rate contribution is made by a simultaneous dark reaction have been rigorously analyzed. Using this analysis and the relevant experimental data, the velocity coefficients of the rate con trolling propagation and termination reactions have been separately evaluated for cyclohexene, 1-methylcycfohexene, dihydromyrcene and
doi:10.1098/rspa.1948.0126
fatcat:u7k4ipy7c5esrdxok3vy3s4mxe