Crystal structure of Tutton's salts, Cs2[MII(H2O)6](SO4)2, MII = Mg, Mn, Fe, Co, Ni, Zn

H. Euler, B. Barbier, A. Meents, A. Kirfel
2003 Zeitschrift für Kristallographie - New Crystal Structures  
Cs2H12MgO14S2, monoclinic, P121/a1 (No. 14), a = 9.338(2) Å, b = 12.849(4) Å, c = 6.361(2) Å, b = 107.07(2)°, V = 729.6 Å 3 , Z = 2, R gt(F) = 0.017, wRref(F 2 ) = 0.041, T = 293 K. Cs 2H12MnO14S2, monoclinic, P121/a1 (No. 14), a = 9.418(3) Å, b = 12.963(2) Å, c = 6.386(3) Å, b = 107.17(4)°, V = 744.9 Å 3 , Z = 2, R gt(F) = 0.017, wRref(F 2 ) = 0.030, T = 293 K. Cs 2FeO14H12S2, monoclinic, P121/a1 (No. 14), a = 9.357(2) Å, b = 12.886(2) Å, c = 6.381(1) Å, b = 106.94(1)°, V = 736.0 Å 3 , Z = 2,
more » ... 736.0 Å 3 , Z = 2, R gt(F) = 0.015, wRref(F 2 ) = 0.030, T = 293 K. CoCs 2H12O14S2, monoclinic, P121/a1 (No. 14), a = 9.318(1) Å, b = 12.826(3) Å, c = 6.3650(9) Å, b = 107.13(1)°, V = 727.0 Å 3 , Z = 2, R gt(F) = 0.021, wRref(F 2 ) = 0.049, T = 293 K. Cs 2H12NiO14S2, monoclinic, P121/a1 (No. 14), a = 9.259(2) Å, b = 12.767(2) Å, c = 6.358(1) Å, b = 107.00(2)°, V = 718.7 Å 3 , Z = 2, R gt(F) = 0.014, wRref(F 2 ) = 0.027, T = 293 K. Cs 2H12O14S2Zn, monoclinic, P121/a1 (No. 14), a = 9.314(2) Å, b = 12.817(2) Å, c = 6.369(2) Å, b = 106.94(2)°, V = 727.3 Å 3 , Z = 2, R gt(F) = 0.015, wRref(F 2 ) = 0.033, T = 293 K.
doi:10.1524/ncrs.2003.218.4.409 fatcat:hf36ntc6jzberomccvjuyakawu