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Analysis of Fe segregation in the octahedral sheet of bentonitic illite-smectite by means of FTIR, 27 Al MAS NMR and reverse Monte Carlo simulations
American Journal of Science
A series of bentonite illite/smectite with a range of Fe content (0.08-0.95 atoms per half formula unit) and illite composition (3-97 percent illite) has been analyzed by means of FTIR, 27 Al MAS NMR, and theoretical calculations by reverse Monte Carlo simulations to study cation distribution in the octahedral sheet. FTIR was used to determine the proportion of different cation pairs bound to OH groups utilizing the OH bending bands. The proportions of cation pairs were used to generate Montedoi:10.2475/ajs.299.4.289 fatcat:pbo2v3pjyrfafis4xx7dfgrv24