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AbstractThermal-stimuli responsive nanomaterials hold great promise in designing multifunctional intelligent devices for a wide range of applications. In this work, a reversible isomeric transformation in an atomically precise nanocluster is reported. We show that biicosahedral [Au13Ag12(PPh3)10Cl8]SbF6 nanoclusters composed of two icosahedral Au7Ag6 units by sharing one common Au vertex can produce two temperature-responsive conformational isomers with complete reversibility, which forms thedoi:10.1038/s41467-020-19789-4 pmid:33243987 fatcat:sqwslbzxi5ehxdwt6linyfpj5i