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New molecular and thermal diffusion coefficients of binary mixtures of normal decane-normal alkanes and methylnaphthalene-normal alkanes are measured at atmospheric pressure and T ) 25°C. The normal alkanes used in this work include nC 5 -nC 20 . Thermal diffusion coefficients were measured in a thermogravitational column. Molecular diffusion coefficients were measured using an open-ended capillary tube technique. Results show a significant effect of molecular shape and size on thermal anddoi:10.1063/1.1924503 pmid:16008457 fatcat:ic3cog4m7fdvxb4uuxsweeyciu