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Topics in catalysis
By means of a combined experimental and computational approach, we show that a 2D metal-organic framework selfassembled at the Au(111) termination is able to mimic the O 2 stabilization and activation mechanisms that are typical of the biochemical environment of proteins and enzymes. 5,10,15,20-tetra(4-pyridyl)21H,23H-porphyrin cobalt(III) chloride (CoTPyP) molecules on Au(111) bind dioxygen forming a covalent bond at the Co center, yielding charge injection into the ligand by exploiting thedoi:10.1007/s11244-020-01333-9 fatcat:siazcp4rjvbmjibbq5afinqqaq