Characterization and Reactivity Study of Non-Heme High-Valent Iron-Hydroxo Complexes

Kritika Keshari, Moumita Bera, Lucia Velasco, Sandip Munshi, Geetika Gupta, Dooshaye Moonshiram, Sayantan Paria
2021 Chemical Science  
A terminal FeIIIOH complex, [FeIII(L)(OH]2– (1), has been synthesized and structurally characterized (H4L = 1,2-bis(2-hydroxy-2-methylpropanamido)benzene). The oxidation reaction of 1 with one equiv. of tris(4-bromophenyl)ammoniumyl hexachloroantimonate (TBAH) or ceric ammonium...
doi:10.1039/d0sc07054h pmid:34163706 pmcid:PMC8179568 fatcat:s3jqwoedyvbmvl7x4gxofgek7m