The Statistical Mechanics of Dynamic Pathways to Self-Assembly

Stephen Whitelam, Robert L. Jack
2015 Annual review of physical chemistry (Print)  
We describe some of the important physical characteristics of the 'pathways', i.e. dynamical processes, by which molecular, nanoscale and micron-scale self-assembly occurs. We highlight the fact that there exist features of self-assembly pathways that are common to a wide range of physical systems, even though those systems may be different in respect of their microscopic details. We summarize some existing theoretical descriptions of self-assembly pathways, and highlight areas -- notably, the
more » ... escription of self-assembly pathways that occur 'far' from equilibrium -- that are likely to become increasingly important.
doi:10.1146/annurev-physchem-040214-121215 pmid:25493714 fatcat:t5aarg7pfremvdkng7oot3zuwu