Two photoluminescent crystal architectures with wire frameworks directly assembled by Ag (I) ions

Hong Ya, Wu, Gui-Ping Tan, Sheng Hu, Shan-Ling Tong, Yan Yan
unpublished
Two novel crystal architectures with wire frameworks, [Ag 2 (btc)(im)] n (1) and [Ag 3 (btc)(im)H 2 O] n (2) (btc = 1, 3, 5-benzene tricarboxylic acid, im = imidazole), have been assembled by hydrothermal method and characterized by X-ray diffractions, elemental analysis, fluorescence spectra and thermal gravimetric analyses (TGA), respectively. Using silver sulfate, complex 1 was arranged as "zigzag" chains of silver ions, while using silver nitrate, complex 2 was presented as straight Ag
more » ... as straight Ag wires. In addition, both complexes exhibit photoluminescence and conductivity at room temperature. 
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