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Silane Oxidation Catalyzed by Carbon Nanotube-Gold Nanohybrids
Significance: The gold nanohybrid on multiwalled carbon nanotubes 1 (AuCNT nanohybrids) was prepared by layer-by-layer (LBL) assembly of amphiphilic nitrilotriacetic acid diyne lipids (DANTA), cationic poly(diallyldimethylammonium chloride) (PDA-DMAC), and colloidal nanoparticles (AuNPs). The AuCNT-catalyzed aerobic oxidation of silanes (2a-j) was carried out in THF to give the corresponding silanols (3a-j) in 93-99% yields. Comment: The hydrophobic portion of DANTA was adsorbed on thedoi:10.1055/s-0031-1289248 fatcat:urqeoco5vbe7fpnpwoh6z7mnje