Backbone-induced semiconducting behavior in shortDNAwires

Gianaurelio Cuniberti, Luis Craco, Danny Porath, Cees Dekker
2002 Physical Review B (Condensed Matter)  
We propose a model Hamiltonian for describing charge transport through short homogeneous double stranded DNA molecules. We show that the hybridization of the overlapping pi orbitals in the base-pair stack coupled to the backbone is sufficient to predict the existence of a gap in the nonequilibrium current-voltage characteristics with a minimal number of parameters. Our results are in a good agreement with the recent finding of semiconducting behavior in short poly(G)-poly(C) DNA oligomers. In
more » ... rticular, our model provides a correct description of the molecular resonances which determine the quasi-linear part of the current out of the gap region.
doi:10.1103/physrevb.65.241314 fatcat:ku54gid7djgh5locn6mc3ds62a