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Yttrium-catalysed dehydrocoupling of alanes with amines
2014
Chemical Communications
Preserved Fulltext
We report [Y{N(SiMe 3 ) 2 } 3 ] as a precatalyst for the 5 dehydrocoupling of sterically demanding amines with βdiketiminate stabilised aluminium dihydrides. While simple anilines readily undergo Al-H/N-H dehydrocoupling under thermal conditions, catalytic methods are required to achieve reasonable rates of reaction for ortho-substituted anilines or 10
doi:10.1039/c4cc04484c
pmid:25011664
fatcat:le2wpq44jzfxbnz2evw722zwiy