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Anhydrous Proton-Conducting Liquid-Crystalline Materials Based on Brønsted Acid-Base Pairs
ブレンステッド酸塩基対に基づく無水プロトン伝導性液晶材料
2019
Preprints of symposium on liquid crystals
ブレンステッド酸塩基対に基づく無水プロトン伝導性液晶材料
Preserved Fulltext
The use of self-assembly of ionic liquid-crystalline molecules is a powerful approach to the formation of ion transport nanochannels. We herein present a series of anhydrous proton-conducting liquid crystals based on Brønsted acid-base pairs. Taper-shaped sulfonic acids are synthesized. Complexation of the sulfonic acids with imidazole stabilizes the liquid-crystalline phases and induces the drastic structural change. For example, the equimolar complex of the sulfonic acid tethering a
doi:10.11538/ekitou.2019.0_pb25
fatcat:7djqwdegv5dfpksczm3glw6zuy