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Excited Dissociation Kinetics of H2O by Pulsed Streamer Discharge
2008
Wuli huaxue xuebao
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OHradical,and(n=3寅n=2)forHatom,respectively.Thetemporal鄄resolvedmeasurementsat 337.2,308.4,656.5nmshowedthattheoccurrencesof •OH * andH * were7.4nsand17.6nslaterthanthatofN 2 * respectively.SothedissociationprocessofH 2 OcanbedescribedasthatH 2 Oisexcitedtohighvibrationallevelofthe firstexcitedstatebynon鄄elasticitycollisionwithelectron,andthendissociatesto•OH * radicalatexcitedstateandH atomatgroundstate.Furthermore,spatial鄄resolvedmeasurementsshowedthatthedensitiesofactiveparticlesreached
doi:10.3866/pku.whxb20080834
fatcat:33vo6q2rvbhktntalr6he4jlu4