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Structural elements of the arylglycerol -syringyl ether type are very frequent in hardwood lignins. A variety of crystalline dimeric lignin models representing different diastereomeric forms of structural elements in lignin of this type have been studied using X-ray crystallography. Bond distances and bond angles in the model compounds are in all probability nearly identical with those of the corresponding structural elements in lignins. Special attention was paid to the geometry of thedoaj:58c066b5034c4135b17cb7c049e25d36 fatcat:srtiaqhh3relzlf3svqtsc7hci