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Significance: The formation of metal enolates allows for precise enolization, as well as potential enantio-and diastereoselective enolization. In this report, the authors apply this idea to a coppercatalyzed conjugate boration-aldol cyclization sequence to produce enantioenriched decalin-, hydrindane-and diquinone-based products. Categor y Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions Key words conjugate boration aldol cyclization copper domino reaction This document wasdoi:10.1055/s-0032-1317775 fatcat:i5zw34edpjdtvjt5nnnd7lke4y