In the development of natural gas reservoirs, the water produced in wells will cause a decline in gas well productivity. In this study, a selective frozen gel plugging agent system suitable for water plugging in gas reservoirs under conditions of high temperature and high salinity. The plugging capacity of the gel system was evaluated. The experimental results showed that: (1) the optimal experimental scheme of the frozen gelling system was as follows: 107 °C with 1.0% AM-AMPS +0.6%

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... l +0.6% hexamethylenetetramine +0.2% thiourea. (2) The optimal injection volume of the system for water phase plugging was 0.5 PV, and the system has an excellent plugging effect at a permeability of 356–3118 mD. (3) The system could also effectively improve the degree of heterogeneity, and the smaller the degree of heterogeneity, the better the improvement effect. (4) The gel system had a good effect on different plugging methods, and the gas medium did not affect the plugging performance. This study provides a sufficient theoretical basis for the exploitation of high-temperature and high-salinity water-bearing gas reservoirs through experimental research, which is of great significance for improving production capacity.