Self-Similarity and Energy Dissipation in Stepped Polymer Films

Joshua D. McGraw, Thomas Salez, Oliver Bäumchen, Elie Raphaël, Kari Dalnoki-Veress
2012 Physical Review Letters  
The surface of a thin liquid film with nonconstant curvature is unstable, as the Laplace pressure drives a flow mediated by viscosity. We present the results of experiments on one of the simplest variable curvature surfaces: a stepped polymer film. Height profiles are measured as a function of time for a variety of molecular weights. The evolution of the profiles is shown to be self-similar. This self-similarity offers a precise measurement of the capillary velocity by comparison with numerical
more » ... ison with numerical solutions of the thin film equation. We also derive a master expression for the time dependence of the excess free energy as a function of the material properties and film geometry. The experiment and theory are in excellent agreement and indicate the effectiveness of stepped polymer films to elucidate nanoscale rheological properties.
doi:10.1103/physrevlett.109.128303 pmid:23005996 fatcat:6alc2elqsfde5a74jb5623zxiq