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Ligand Stabilization of Manganocene Dianions – In Defiance of the 18-Electron Rule
2019
Physical Chemistry, Chemical Physics - PCCP
Manganocene [Mn(C5H5)2], a 17-electron system, is expected to have a high electron affinity, as addition of an extra electron would make it a closed-shell 18-electron system. Surprisingly, it has a...
doi:10.1039/c9cp02331c
fatcat:blmdiem2mjb6hbdtxguakw4aay