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Polarization‐resolved (2+1) resonance‐enhanced multiphoton ionization spectroscopy of CF3I (6s) Rydberg states
1993
Journal of Chemical Physics
The CF,I( 5pr-6s) Rydberg transitions in the energy range 56 700-64 000 cm-' are investigated using (2+ 1) resonance-enhanced multiphoton ionization. The polarization of the twophoton transitions is used to definitely assign the symmetries of the resonant intermediate states. The four allowed electronic transitions in the (5p~--6s) manifold have been assigned and some vibrational constants in the excited states have been determined. Hot band spectra have been obtained in a supersonic expansion
doi:10.1063/1.464997
fatcat:uvkmm2b7wjfedd22qkm54e5rne