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Synthesis and Characterization of Dinuclear Metal Complexes Stabilized by Tetradentate Schiff Base Ligands
American Journal of Applied Sciences
Problem statement: The synthesis, spectroscopic properties and theoretical calculations of acetylacetonimine and acetylacetanilidimine Schiff-base ligands, L 1 H and L 2 H, respectively and their dinuclear complexes of the type [M 2 L n Cl 2 (H 2 O) 2 ], where n = 1 or 2, M = Co(II), Ni(II), Cu(II), Zn(II) and Cd(II) are described. Approach: The new tetradentate dianion Schiff base ligand which was used as stabilizers for the complexes were prepared by condensation of hydrazine withdoi:10.3844/ajassp.2010.628.633 fatcat:dnlbgjsj2fc63lcosnhx6ru64m