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Synthesis and structures of bis(alkyldihydroxysilyl)methanes
2005
Journal of Organometallic Chemistry
Bis(alkyldihydroxysilyl)methanes 1 [R(HO) 2 SiCH 2 Si(OH) 2 R: R = methyl (a) and cyclopentyl (b)] were prepared in 65% and 86% yields by the hydrolysis of the corresponding bis(alkyldichlorosilyl)methanes using aniline as HCl scavenger in diethyl ether. They were isolated in pure forms, fully characterized, and studied on their thermal properties. In single crystal X-ray structures, the molecules of 1a and 1b crystallize in the tetragonal (a = b = 22.884 Å , c = 6.1485 Å ; a = b = c = 90°in a
doi:10.1016/j.jorganchem.2005.07.106
fatcat:udhoopy2c5hifen5orkeluidpe