A copy of this work was available on the public web and has been preserved in the Wayback Machine. The capture dates from 2017; you can also visit the original URL.
The file type is
Bis(alkyldihydroxysilyl)methanes 1 [R(HO) 2 SiCH 2 Si(OH) 2 R: R = methyl (a) and cyclopentyl (b)] were prepared in 65% and 86% yields by the hydrolysis of the corresponding bis(alkyldichlorosilyl)methanes using aniline as HCl scavenger in diethyl ether. They were isolated in pure forms, fully characterized, and studied on their thermal properties. In single crystal X-ray structures, the molecules of 1a and 1b crystallize in the tetragonal (a = b = 22.884 Å , c = 6.1485 Å ; a = b = c = 90°in adoi:10.1016/j.jorganchem.2005.07.106 fatcat:udhoopy2c5hifen5orkeluidpe