H2Fuels from Photocatalytic Splitting of Seawater Affected by Nano-TiO2Promoted with CuO and NiO

A.-J. Simamora, Fang-Chih Chang, H. Paul Wang, T.-C. Yang, Y.-L. Wei, W.-K. Lin
2013 International Journal of Photoenergy  
To enhance H2yields from the photocatalytic splitting of seawater, better photocatalysts such as nanostructured TiO2promoted with NiO (2.5%) and CuO (2.5%) have been studied in the present work. The accumulated H2yielded from the photocatalytic splitting of seawater containing oxalic acid (50 mM) as the sacrificial reagents on CuO/nano-TiO2is 8.53 μmol/gcatafter the 5 h radiation. On the NiO/nano-TiO2photocatalyst, the H2yield is relatively low (i.e., 1.46 μmol/gcat). Note that the hole
more » ... ng with chlorides in seawater may be associated with the less H2yielded from the seawater photocatalysis (on CuO/nano-TiO2) if compared with that from water (42.4 μmol/gcat).
doi:10.1155/2013/419182 fatcat:hjgkpfdarnbdnlr3mgdzyngwge