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Regioselective Fluoroalkylphosphorylation of Unactivated Alkenes via Radical–Mediated Alkoxylphosphane Rearrangement
[post]
2022
unpublished
A regioselective radical fluoroalkylphosphorylation of unactivated alkenes has been developed by a one-pot twosteps reaction of (bis)homoallylic alcohols, organophosphine chlorides (R2PCl), and fluoroalkyl iodides (RFI) under visible light irradiation. This protocol employs the radical rearrangement of the in situ formed alkoxyphosphane for the first time to regiospecific installing a phosphonyl group onto the inner carbon of terminal olefins in alkene difunctionalization via C-P bond formation
doi:10.26434/chemrxiv-2022-vnh52
fatcat:fgjnz6zdlfertkae23rvuazhaa