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Proton NMR Relaxation in Hydrous Melts
ECS Proceedings Volumes
Pulse and continuous wave NMR measurements are reported for protons in hydrous melts of calcium nitrate at tempera tures between -k° and 120°C. Although measured in different temperature ranges, spin-lattice (Tp) and spin-spin (T2 ) re laxation times appear to be nearly equal to each other and proportional to the self-diffusion coefficients of solute metal cations such as Cd2+. At temperatures near 50°C mean Arrhenius coefficients, A Hp, (kcal/mol), are 7 .9 , 7 .3 , and U.8, respectively, fordoi:10.1149/197606.0544pv fatcat:dmwlxbcwtzdyxeaf2zgfxj26dq