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Development of the Asymmetric Cycloaddition Reactions and Asymmetric Nucleophilic Addition Reaction Utilizing Tartaric Acid Esters
1998
Journal of Synthetic Organic Chemistry, Japan
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In order to develop a practical method for the construction of chiral molecules , we have designed a novel chiral system possessing two metal centers utilizing tartaric acid esters : that is, if two reactants are bound to the two metal centers of a dialkoxide derived from tartaric acid ester, they might be ideally oriented and/or activated by the metals and the subsequent reaction can proceed in an enantioselective manner to afford the corresponding optically active products. According to this
doi:10.5059/yukigoseikyokaishi.56.11
fatcat:5usnuqthyrbolkk26jhq4fww3a