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An ESR Study of Mn(II) Complexes in Water-Methanol Mixed Solvents
Zeitschrift für Naturforschung. B, A journal of chemical sciences
0.01 ᴍ solutions of Mn (ClO4)2, MnCl2 and MnSO4 in water-methanol mixtures were studied at 25 °C to determine the effect of these anions and of solvent composition on the ESR intensity and linewidth of Mn(II). A significant feature of the data was the large difference between the intensity of Mn(ClO4)2 and that for MnCl2 and MnSO4 in solutions containing greater than about 0.5 mole fraction methanol. A plot of linewidth versus mole fraction methanol shows little difference between Mn(ClO4)2 anddoi:10.1515/znb-1971-1102 fatcat:hh3va3ct7ravnem7dprrmndmyi