A new method for cross-metathesis of terminal olefins

Daniel J O'Leary, Helen E Blackwell, Rebecca A Washenfelder, Robert H Grubbs
<span title="">1998</span> <i title="Elsevier BV"> <a target="_blank" rel="noopener" href="https://fatcat.wiki/container/piqjj4fvzrearppde23jka7lie" style="color: black;">Tetrahedron Letters</a> </i> &nbsp;
A new method for the cross-metathesis of terminal olefins is described. Treatment of terminal olefins with 1-2 equivalents of a symmetric disubstituted cis or trans olefin and 5 mol% C12(PCy3)2Ru=CHPh (1) in dichloromethane generates the desired cross-metathesis products in good yield.
<span class="external-identifiers"> <a target="_blank" rel="external noopener noreferrer" href="https://doi.org/10.1016/s0040-4039(98)01647-5">doi:10.1016/s0040-4039(98)01647-5</a> <a target="_blank" rel="external noopener" href="https://fatcat.wiki/release/t3qahxcxyfbbdjfvfinfi5ndh4">fatcat:t3qahxcxyfbbdjfvfinfi5ndh4</a> </span>
<a target="_blank" rel="noopener" href="https://web.archive.org/web/20060924104958/http://www.gps.caltech.edu/~rebeccaw/publications/OLeary_1998_TetLet_New_method_for_cross_metathesis_of_terminal_olefins.pdf" title="fulltext PDF download" data-goatcounter-click="serp-fulltext" data-goatcounter-title="serp-fulltext"> <button class="ui simple right pointing dropdown compact black labeled icon button serp-button"> <i class="icon ia-icon"></i> Web Archive [PDF] <div class="menu fulltext-thumbnail"> <img src="https://blobs.fatcat.wiki/thumbnail/pdf/25/bf/25bfa3a7e4ae764101412d1e369ae3016498a4dd.180px.jpg" alt="fulltext thumbnail" loading="lazy"> </div> </button> </a> <a target="_blank" rel="external noopener noreferrer" href="https://doi.org/10.1016/s0040-4039(98)01647-5"> <button class="ui left aligned compact blue labeled icon button serp-button"> <i class="external alternate icon"></i> elsevier.com </button> </a>