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Elucidating proline dynamics in spider dragline silk fibre using 2H–13C HETCOR MAS NMR
2014
Chemical Communications
2H–13C HETCOR MAS NMR is performed on 2H/13C/15N-Pro enriched A. aurantia dragline silk. Proline dynamics are extracted from 2H NMR line shapes and T1 in a site-specific manner to elucidate the backbone and side chain molecular dynamics for the MaSp2 GPGXX β-turn regions for spider dragline silk in the dry and wet, supercontracted states.
doi:10.1039/c4cc00971a
pmid:24686512
fatcat:dnztqphavbahxi4bdtij25eiui