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The basic approach in the microscopic theory of binary metal systems has been developed. The electron-ion model Hamiltonian with nonlocal manyparticle interactions was obtained using the statistical operator averaging for the electron-nuclear model over the localized electron states. The role of orthogonalization and exchange effects on the formation of electron-ion interactions is investigated. The transition to the ion metal model with effective manyparticle interactions was performed. Keydoi:10.5488/cmp.7.1.101 fatcat:orycvr4wvzd4rc7vkcszth66bi