Stepwise oxidation of three communicating metal centres: electrochemistry of trinuclear trindenyl complexes of manganese or rhodium

Rainer Winter, David T. Pierce, William E. Geiger, Thomas J. Lynch
1994 Journal of the Chemical Society Chemical Communications  
Trinuclear manganese or rhodium complexes of the trindenyl (Td) ligand undergo three separate 1 e--oxidation reactions, with an abnormally large separation in potentials between the second and third oxidations of [Td{Rh 3 (codb} ].
doi:10.1039/c39940001949 fatcat:fxxxbbolgjbf3msw7r7jopqigm