With the aim of increasing the sample of M31 clusters for which a colour magnitude diagram is available, we searched the HST archive for ACS images containing objects included in the Revised Bologna Catalogue of M31 globular clusters. Sixty-three such objects were found. We used the ACS images to confirm or revise their classification and we obtained useful CMDs for 11 old globular clusters and 6 luminous young clusters. We obtained simultaneous estimates of the distance, reddening, and

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... ity of old clusters by comparing their observed field-decontaminated CMDs with a grid of template clusters of the Milky Way. We estimated the age of the young clusters by fitting with theoretical isochrones. For the old clusters, we found metallicities in the range -0.4<=[Fe/H]<=-1.9, that generally agree with existing spectroscopic extimates. At least four of them display a clear blue HB, indicating ages >10 Gyr. All six candidate young clusters are found to have ages <1Gyr. With the present work the total number of M31 GCs with reliable optical CMD increases from 35 to 44 for the old clusters, and from 7 to 11 for the young ones. The old clusters show similar characteristics to those of the MW. We discuss the case of the cluster B407, with a metallicity [Fe/H] ~-0.6 and located at a large projected distance from the centre of M31 and from the galaxy major axis. Metal-rich globulars at large galactocentric distances are rare both in M31 and in the MW. B407, in addition, has a velocity in stark contrast with the rotation pattern shared by the bulk of M31 clusters of similar metallicity. This, along with other empirical evidence, supports the hypothesis that the cluster is physically associated with a substructure in the M31 halo that has been interpreted as the relic of a merging event.