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Visualizing Structural Transformation and Guest Binding in a Flexible Metal–Organic Framework under High Pressure and Room Temperature
2018
ACS Central Science
Understanding the effect of gas molecules on the framework structures upon gas sorption in porous materials is highly desirable for the development of gas storage and separation technologies. However, this remains challenging for flexible metal−organic frameworks (MOFs) which feature "gate-opening/gate-closing" or "breathing" sorption behaviors under external stimuli. Herein, we report such a flexible Cd-MOF that exhibits "gating effect" upon CO 2 sorption. The ability of the desolvated
doi:10.1021/acscentsci.8b00378
pmid:30276253
pmcid:PMC6161039
fatcat:ch4qfdme6rdu3gwg346dmlrf4i