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Ultrasonic spray-pyrolysis technique may be effective for syntheses of the HAp and various substituted apatites powders with the formula of M 10 (PO 4 ) 6 (OH) 2 (M=Ca, Sr, Ca+Sr and Ba). We have reviewed our research for 1) syntheses of HAp and substitued apatite powders by spray-pyrolysis technique and 2) coating process for porous films with good biocompatibility based on the above technique. Spray-pyrolysis technique is also effective for porous coating of biocompatible calcium-phosphatedoi:10.3363/prb.20.61 fatcat:aj257ad3xrhspjip3xfctvy4ai