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Tunable supramolecular networks via cis-trans metal–ligand isomerization
2010
Soft Matter
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Angle distribution and energy consideration As shown in Figure 1 in the main text, for cisand transisomers there are different preferable angles between ligands in 2:1 ligand-metal complexes: θ 0 =120° and θ 0 =180° respectively 1 ; while in 3:1 ligand-metal complexes ligands are homogeneously distributed around the metal with an average angle between any two ligands θ 0 =120°. In our Monte Carlo simulations a reversible coordination bond between a metal and a ligand is formed during a bonding
doi:10.1039/b919491f
fatcat:kw4d2ext35atxcyahf33hslsxy